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Analysis of the phonon spectrum in the titanium oxyhalide TiOBr

机译:卤氧化钛TiOBr中的声子谱分析

摘要

We present the electrodynamic response of TiOBr, which undergoes a transitionto a spin-singlet ground state for temperatures below T$_{C1}=28$ K. Thetemperature evolution of the phonon anomalies indicates, like in \cl, anextended fluctuation regime, extending well above T$_{C1}$. At low frequencies,the spectral weight is progressively suppressed by decreasing the temperature,suggesting the formation of a spin-gap and a considerable electron-phononcoupling. A comparison of the two oxyhalides shows a weaker interplane couplingand reduced dimensionality for TiOBr that enhances fluctuations and shifts theordering temperatures to lower values. In the fluctuation regime thetemperature dependencies of some phonon parameters track the temperatureevolution of the magnetic susceptibility.
机译:我们介绍了TiOBr的电动力响应,当温度低于T $ _ {C1} = 28 $ K时,它经历了转变为自旋单基态。声子异常的温度演化表明,像在\ cl中一样,扩展了涨落范围,远高于T $ _ {C1} $。在低频下,通过降低温度来逐步抑制频谱权重,这建议形成自旋间隙和相当大的电子-声子耦合。两种卤氧化物的比较表明,TiOBr的平面间耦合较弱,尺寸减小,这会增加波动并将有序温度移至较低值。在起伏状态下,一些声子参数的温度依赖性跟踪磁化率的温度演化。

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